post work out meaning after! your muscles begin to absorb during 30 mins after your workout meaning a protein shake would be best sufficient during that time. Also don't forget a post workout meal especially after a good workout. Look into casein protein which is basically a time released protein which is best before you go to bed.
Muscle milk may taste good but its full of unnecessary ingredients that you really don't need. I recommend ON whey.
Hope that helps
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